Radiocarbon dating works by knowing what portion of carbon-14 (an unstable radioactive isotope of carbon) remains present in an organic sample.
Plants and animals that eat plants take in carbon-14 and normal carbon in measurable proportions, and then when they die they stop taking in more new carbon 14, the ratio of carbon-14 to carbon then changes over time at a measureable rate we can use to determine the age of objects to about 60,000 years ago.
We didn't use carbon dating to determine the age of theia because all traces of carbon-14 would be long gone after 14 billion years.
I'm not familiar enough to speculate further, other methods of radiometric dating would likely have been used alongside other methods to determine the age of theia. Other radiometric methods use similar methods where we know the decay rate of certain radioactive materials, but for different date and age ranges than carbon.