Lets say you have a 300mi range EV. that sounds great, until you realize you can't actually use it all.
We like to save the bottom 20% for emergencies and battery longevity, and fast charging is too slow above 80% to be worth it, so effectively, on a road trip. only the 20%-80% range is usable. Your 300mi+ range just turned into 180mi of usable range. And then factor in ~10% battery degradation over time, or range reduction in winter conditions, and you could easily have as little as 150mi of actual usable range between charging stops. And that's assuming the charging stations are perfectly spaced apart.
That's only a little more than 2 hours at highway speeds. And that's not along time to be driving, even for a single person. In gas cars, we will regularly do 3-4 hours without stopping at all. And if we do stop for a break, it's rarely at gas stations or places with charging stations. Those are typically awful places to spend the limited amount of time you have on a trip.
In practice, the charging interval is far, far less than the ideal 300mi and far more frequent.